Serveur d'exploration sur le nickel au Maghreb

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AgNi3(PO4)(HPO4)2: an alluaudite‐like structure

Identifieur interne : 000A05 ( Main/Exploration ); précédent : 000A04; suivant : 000A06

AgNi3(PO4)(HPO4)2: an alluaudite‐like structure

Auteurs : Ridha Ben Smail [Tunisie] ; Tahar Jouini [Tunisie]

Source :

RBID : ISTEX:C00132578099ADC2B8DC1900BD5FCE1D69CAFEF0

Abstract

The new title phosphate, silver trinickel phosphate bis(hydrogenphosphate), has been synthesized by the hydro­thermal method. It has an alluaudite‐like structure but shows some differences owing to the presence of the H atoms. The structure is isomorphous with the compounds of general formula AM3(XO4)(HXO4)2 (A is Na or Ag, M is Co, Zn or Mn, and X is As or P), with the Ag atom, one Ni atom and one P atom lying on twofold axes.

Url:
DOI: 10.1107/S0108270102003153


Affiliations:


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